副研究员

  博士生导师

 文化遗产保护基础科学研究院 副院长

  Email：fxbu@shu.edu.cn

研究方向：新型文保和能源材料研发与应用研究
1. 硅氧烷、氢氧化钙和磷酸钙等矿物低聚物的可控设计和仿生矿化研究
2. MOFs和COFs等介孔材料的设计合成及介微孔化学研究
3. MXenes、硅烯、石墨烯、粘土等二维材料的宏量制备科学及维度效应研究

个人简介：

长期从事新型介孔材料（MOFs、COFs等）、二维材料（MXenes、硅烯、石墨烯、粘土等）和低聚物胶凝材料的设计合成和功能应用开发研究。师从复旦大学赵东元院士，入选Journal of Materials Chemistry A新锐科学家，担任Carbon Neutralization青年编委和石窟和土遗址保护专业委员会委员等。先后主持中国博士后科学基金特等资助等科研项目7项，参与国家自然科学基金和国际合作项目多项。共发表SCI论文50余篇，其中以第一作者和通讯作者在J. Am. Chem. Soc., Adv. Mater.（2）, Angew. Chem. Int. Ed.（3）, Natl. Sci. Rev.（2）, Energy Environ. Sci, Adv. Funct. Mater. (1)、ACS Nano (3)、Nano Today、Chem. Eng. J、J. Mater. Chem. A、J. Cult. Heritage，npj Herit. Sci.等期刊上发表论文30余篇，其中4篇入选ESI高被引论文，总引用超过4200次。同时申请发明专利20余项。

教育背景：

2007-2011，本科，武汉理工大学材料学院

2011-2016，博士，华东师范大学物理系，（导师：姜继森教授）

工作经历：

2016-2018，博士后，复旦大学高分子系，（合作导师：徐宇曦教授）

2018-2021，博士后，复旦大学先进材料实验室，（合作导师：赵东元院士、晁栋梁教授）

科研论文：

1. F. Zhu, Z. Zhang, F.-X. Bu,* D. Chao.* Breaking the shuttle limitation in aqueous halogen batteries toward durable energy storage systems. Natl. Sci. Rev. 2026, nwag459.
2. F. Yang, T. Zhang,* F.-X. Bu,* D. Chao,* D. Zhao,* et al. Interfacial Lewis Acid Chemistry Enabled by Mesoporous MOFs Toward High-Performance Four-Electron Zinc-Iodine Batteries. Angew. Chem. Int. Ed. 2026, e3627132.
3. Y. Wan,† B. Wang,† R. Li,† Y. Liu,† F.-X. Bu,* D. Chao,* D. Zhao,* W. Luo,* et al. Versatile interfacial-energy-driven emulsion assembly synthesis of large-pore mesoporous covalent organic frameworks for accelerated Zn2+ desolvation in aqueous battery. Natl. Sci. Rev. 2026, 13.
4. Y. Wan,† L. Huang,† F.-X. Bu,* D. Chao,* D. Zhao,* W. Luo,* et al. Large-pore mesoporous covalent organic frameworks as fast ion sieves via kinetics-mediated micelle assembly for aqueous batteries. Energy Environ. Sci. 2026, 19, 3944-3955.
5. Y. Chen,† J. He,† M. Li, H. Shen, C. Han, Y. Tian, F.-X. Bu,* Z. Li.* et al. Regulation of Interfacial Ion Transport via Honeycomb-Architected Covalent Organic Frameworks for Lithium Metal Batteries. Adv. Mater. 2025, e12997.
6. X. Wang, S. Zhang, M. Li, S. Hu, F.-X. Bu,* D. Chao,* W. Luo,* et al. Tailored Design of Mesoporous Metal Organic Framework Single Crystals by Kinetics-Mediated Micelle Assembly for Efficient Asymmetrical Single-Atom Catalysis. Adv. Mater. 2025, 2500370.
7. J. Chen, G. Li, F.-X. Bu,* D. Chao,* D. Zhao,* et al. Tandem Assembly and Etching Chemistry towards Mesoporous Conductive Metal-Organic Frameworks for Sodium Storage over 50,000 Cycles. Angew. Chem. Int. Ed. 2025, e202500287.
8. Z. Sun†, F.-X. Bu,† Y. Zhang, D. Zhao, Y. Wang,* D. Chao,* et al. Electron-Donating Conjugation Effect Modulated Zn2+ Reduction Reaction for Separator-Free Aqueous Zinc Batteries. Angew. Chem. Int. Ed. 2024, 63, e202402987. (ESI高被引论文)
9. F.-X. Bu, Z. Sun, W. Zhou, A. Elzatahry*, D. Chao,* D. Zhao,* et al. Reviving Zn0 Dendrites to Electroactive Zn2+ by Mesoporous MXene with Active Edge Sites. J. Am. Chem. Soc. 2023, 145, 24284-24293. (ESI高被引论文)
10. T. Zhao, X. Wang, P. Qiu, Q. Xiao, W. Jiang, L. Wang, F.-X. Bu,* W. Luo,* et al. Hollow Mesoporous Metal Organic Framework Single Crystals Enabled by Growth Kinetics Control for Enhanced Photocatalysis. Adv. Funct. Mater. 2023, 2303644.
11. R. Li, Z. An, Y. Wan, Z. Zhu, J. Huang, D. Chao, X. Zhang, W. Luo, T. Jiang,* F.-X. Bu,* Precisely controlling coexisting negative and positive photoconductance via MXene-derived heterojunctions for self-powered and flexible multi-modal optoelectronic logic gates. Chem. Eng. J. 2025, 170311.
12. Y. Cheng, Z. Li, W. Yang, R. Li, L. Huang, Z. Zhu, R. Yang, T. Chen, L. Wang, J. Huang, F.-X. Bu,* Phenyl grafted flexible-rigid hybrid organosilicon network with enhanced aging- and crack-resistance for sandstone cultural heritage conservation. J. Cult. Heritage 2026, 82, 124-135.
13. W. Yang, Z. Li, Y. Cheng, R. Yang, R. Li, Z. Zhu, J. Huang, F.-X. Bu,* Siloxane-Schiff Base Dual-Crosslinking Enable Damage-Free Consolidation of Fragile Waterlogged Ivory From the Sanxingdui Site. Archaeometry 2026, accepted.
14. Z. Li, R. Wang,* F.-X. Bu,* J. Huang.* Hybrid siloxane oligomer: A promising consolidant for the conservation of powdered tremolite jade artifacts. J. Cult. Heritage 2024, 70, 388-396.
15. H. Wu, R. Li, Z. Zhu, J. Huang, F.-X. Bu,* et al. Three dimensional calcite consolidation network from calcium ethylene glycol complex solution for stone heritage conservation. npj Herit. Sci. 2025, 13, 128.
16. Z. Li, J. Hu, R. Wang,* F.-X. Bu,* J. Huang,* Mercapto-functionalized siloxane for enhanced conservation of tremolite jade artifacts. npj Herit. Sci. 2025, 13, 212.
17. Z. Li, C. Jia, W. Luo, R. Wang, J. Huang, F.-X. Bu,* et al. Flexible-rigid hybrid siloxane network for stone heritage conservation. J. Cult. Heritage 2024, 69, 148-157.
18. Z. Li, W. Yang, R. Wang,* J. Huang,* F.-X. Bu,* et al. Synergistic Integration of Siloxane Sol-Gel Reactions and Schiff-Base Crosslinking: Constructing Advanced Conservation Coatings for Degraded Silk Artifacts，Appl. Surf. Sci. 2025, 163988.
19. Li, Z.; Yang, W.; Wang, R.; Huang, J.; F.-X. Bu,* et al. Simultaneous Deacidification and Reinforcement of Aged Paper via In Situ Polymerization of Inorganic Ionic Oligomers. Archaeometry 2025, 1-9.
20. J. He, Z. Sun, L. Huang, Z. Zhu, W. Luo,* D. Chao,* F.-X. Bu.* Two-dimensional conductive mesopore engineering of ultrahigh content covalent sulfur-doped carbon for superior sodium storage. J. Mater. Chem. A 2025, 13, 15736-15742.
21. W. Zhu,* B. Zhang, F.-X. Bu,* M. Zhao, X. Tao,* K. Liu, Y. Fang, W. Luo.* 1T-MoS2 nanosheets with enlarged interlayer spacing vertically bonded on rGO for high-performance lithium-ion capacitors. Green Energy Environ. 2025.
22. F.-X. Bu, M. M. Zagho, Y. Ibrahim, B. Ma, A. Elzatahry*, D. Zhao*. Porous MXenes: Synthesis, structures and applications. Nano Today, 2020, 30, 100803. (ESI高被引论文)
23. F.-X. Bu, W. Chen, J. Gu, P. O. Agboola, N. F. Al-Khalli, I. Shakir,* Y. Xu.* Microwave-assisted CVD-like synthesis of dispersed monolayer/few-layer N-doped graphene encapsulated metal nanocrystals for efficient electrocatalytic oxygen evolution. Chem. Sci., 2018, 9, 7009.
24. P Xiao†, F.-X. Bu,† R. Zhao, Y. Xu.* Sub-5 nm Ultrasmall Metal–Organic Framework Nanocrystals for Highly Efficient Electrochemical Energy Storage. ACS Nano, 2018, 12, 3947.
25. T. Jiang†, F.-X. Bu,† X. Feng, I. Shakir,* G. Hao*, Y. Xu.* Porous Fe2O3 Nanoframeworks Encapsulated within Three-Dimensional Graphene as High-Performance Flexible Anode for Lithium-Ion Battery. ACS Nano, 2017, 11, 5140. (ESI高被引论文)
26. Z. Chen,† J. Chen,† F.-X. Bu,† P. O. Agboola, I. Shakir,* Y. Xu.* Double-Holey-Heterostructure Frameworks Enable Fast, Stable, and Simultaneous Ultrahigh Gravimetric, Areal, and Volumetric Lithium Storage. ACS Nano, 2018, 12, 12879.
27. F.-X. Bu, W. Chen, M. F. A. Aboud, I. Shakir,* J. Gu*, Y. Xu.* Microwave-assisted ultrafast synthesis of adjustable bimetal phosphide/graphene heterostructures from MOFs for efficient electrochemical water splitting. J. Mater. Chem. A, 2019, 7, 14526-14535.
28. F.-X. Bu, P Xiao, X. Feng, G. Yang, Y. Xu.* Rational design of three-dimensional graphene encapsulated core–shell FeS@ carbon nanocomposite as a flexible high-performance anode for sodium-ion batteries. J. Mater. Chem. A, 2018, 6, 6414.
29. F.-X. Bu, X. Feng, T. Jiang, I. Shakir,* Y. Xu.* One Versatile Route to Three-Dimensional Graphene Wrapped Metal Cyanide Aerogels for Enhanced Sodium Ion Storage. Chem. Eur. J, 2017, 83, 8358.
30. F.-X. Bu, M. Hu, W. Zhang, Q. Meng, L. Xu, D.- M. Jiang, J.-S. Jiang.* Three-Dimensional Hierarchical Prussian Blue Composed of Ultrathin Nanosheets: Enhanced Hetero-Catalytic, Adsorption Properties. Chem. Commun., 2015, 51, 17568.
31. F.-X. Bu, L. Xu, W. Zhang, C.-Y. Jin, R.-J. Qi, R. Huang, J.-S. Jiang.* A Versatile Strategy to Construct Multifunctional Metal Oxide@Cyanometallate-based Coordination Polymer Heterostructures. Chem. Commun., 2015, 51, 6198.
32. F.-X. Bu, M. Hu, L. Xu, Q. Meng, G.-Y. Mao, D.-M. Jiang, J.-S. Jiang.* Coordination Polymers for Catalysis: Enhancement of Catalytic Activity through Hierarchical Structuring. Chem. Commun., 2014, 50, 8543.
33. L. Xu,† F.-X. Bu,† M. Hu, C.-Y. Jin, D.-M. Jiang, Z.-J. Zhao, Q.-H. Zhang, J.-S. Jiang.* Monocrystalline Mesoporous Metal Oxide with Perovskite Structure: A Facile Solid-State Transformation of A Coordination Polymer. Chem. Commun., 2014, 50, 13849.
34. F.-X. Bu, Y. Xu.* Three-dimensional Graphene Composites for Electrochemical Energy Storage. Adv. Mater. Interfaces, 2018, 5, 1800468.
35. F.-X. Bu, C.-J. Du, Q.-H. Zhang, J.-S. Jiang.* One-Pot Synthesis of Prussian Blue Superparticles from Reverse Microemulsion. CrystEngComm, 2014, 16, 3113.
36. C.-J. Du,† F.-X. Bu,† D.-M. Jiang, Q.-H. Zhang, J.-S. Jiang.* Prussian Blue Analogue K2Zn3[Fe(CN)6]2 Quasi Square Microplates: Large-Scale Synthesis, Their Thermal Conversion into A Magnetic Nanoporous ZnFe2−xO4–ZnO Composite. CrystEngComm, 2013, 15, 10597.
37. F.-X. Bu, C.-J. Du, J.-S. Jiang.* Synthesis, Properties, Applications of Mesocrystals. Prog. Chem., 2014, 26, 75.

科研项目：

1. 国家自然科学项目，介孔MOFs路易斯酸纳米反应器的构筑、结构调控及其催化I+转化机制，在研
2. 国家自然科学基金联合基金重点项目，长江口木质古船生物黏附与盐害的病损机制及相关保护技术研究，在研
3. 山西省科技厅项目，云冈石窟杂化硅氧烷基防风化保护材料研究，在研
4. 横向项目，长江口二号古船文物监测、检测分析评估，在研
5. 横向项目，石油渣高值介孔碳材料的宏量制备及工业催化氢氧复合应用，在研
6. 硅酸盐质教育部重点实验室课题，核壳纳米材料的设计合成及石窟浅表层防风化保护研究，在研
7. 横向项目，天龙山石窟题刻保护前期勘察研究，结题
8. 硅酸盐质教育部重点实验室课题，石窟砂岩粉状风化病害治理研究，结题
9. 中国博士后科学基金第12批特别资助，单胶束组装的有序介孔MXene的合成和电化学储能研究，结题
10. 中国博士后科学基金第11批特别资助，寡层石墨烯壳基异质结的超快制备与催化性能研究，结题
11. 中国博士后科学基金第65批面上资助，MXene量子点：宏量制备，结构控制和高性能电池设计，结题
12. 中国博士后科学基金第62批面上资助，三维石墨烯／金属有机骨架材料基高性能电化学储能材料，结题

其他：

本课题组与复旦大学赵东元院士团队和东华大学杰青团队开展广泛的交流与合作，欢迎报考课题组硕士研究生！